{"data":{"id":"10.6084/m9.figshare.3503567","type":"dois","attributes":{"doi":"10.6084/m9.figshare.3503567","prefix":"10.6084","suffix":"m9.figshare.3503567","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"S. Pramodini Devi","affiliation":[],"nameIdentifiers":[]},{"name":"N. Shantibala Devi","affiliation":[],"nameIdentifiers":[]},{"name":"L. Jaideva Singh","affiliation":[],"nameIdentifiers":[]},{"name":"R. K. Bindiya Devi","affiliation":[],"nameIdentifiers":[]},{"name":"W. Radhapiyari Devi","affiliation":[],"nameIdentifiers":[]},{"name":"Ch. Brajakishore Singh","affiliation":[],"nameIdentifiers":[]},{"name":"R. K. Hemakumar Singh","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Spectroscopic and DNA interaction studies on mixed ligand copper(II) complexes of dicyanamide with ethylenediamine or 1,3-diaminopropane"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Microbiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Cell Biology"},{"subject":"Molecular Biology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Cancer"},{"subject":"111714 Mental Health","subjectScheme":"FOR"},{"subject":"FOS: Health sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Health sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2016-07-27","dateType":"Created"},{"date":"2016-10-17","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/15533174.2016.1158189","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["351408 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Mixed ligand copper(II) complexes of dicyanamide with different polyamines, \u003ci\u003eviz.\u003c/i\u003e ethylenediamine (\u003cb\u003e1\u003c/b\u003e) and 1,3-diaminopropane (\u003cb\u003e2\u003c/b\u003e), have been synthesized and characterized. The crystal structure of complex \u003cb\u003e1\u003c/b\u003e contains a five-coordinated copper in a distorted square-pyramidal environment and forms 1D zig-zag polymeric chain via the bridging ligand dicyanamide. Hydrogen bonding contributes supramolecular architecture in the crystal. Electronic spectral studies suggest the distorted square-pyramidal structure of the complexes. The interaction of the copper(II) complexes with calf-thymus DNA reveals nonintercalative binding mode. The two complexes have antimicrobial activity against the bacteria (\u003ci\u003eviz. Salmonella paratyphi\u003c/i\u003e), which is responsible for paratyphoid 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