{"data":{"id":"10.6084/m9.figshare.3122941.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.3122941.v1","prefix":"10.6084","suffix":"m9.figshare.3122941.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Xiao-Zu Wang","affiliation":[],"nameIdentifiers":[]},{"name":"Xue, Qian","nameType":"Personal","givenName":"Qian","familyName":"Xue","affiliation":[],"nameIdentifiers":[]},{"name":"Liu, Shao-Xian","nameType":"Personal","givenName":"Shao-Xian","familyName":"Liu","affiliation":[],"nameIdentifiers":[]},{"name":"Luo, Hong-Bin","nameType":"Personal","givenName":"Hong-Bin","familyName":"Luo","affiliation":[],"nameIdentifiers":[]},{"name":"Ren, Xiao-Ming","nameType":"Personal","givenName":"Xiao-Ming","familyName":"Ren","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Dielectric anomaly and giant deuteration effect in a H-bond trimeric co-crystal [4, 4’-bipyridine]\u003csub\u003e2\u003c/sub\u003e[1,4-dihydroxybenzene]"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Developmental Biology"},{"subject":"Inorganic Chemistry"},{"subject":"Computational Biology"}],"contributors":[],"dates":[{"date":"2016-03-23","dateType":"Created"},{"date":"2016-03-23","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/1539445x.2016.1159577","relatedIdentifierType":"DOI"},{"relationType":"IsPreviousVersionOf","relatedIdentifier":"10.6084/m9.figshare.3122941","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["3739370 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Co-crystal [4,4’-bipyridine]\u003csub\u003e2\u003c/sub\u003e[1,4-dihydroxybenzene] (\u003cb\u003e1\u003c/b\u003e) was prepared by evaporating methanol solution of 4, 4’-bipyridine with 1, 4-dihydroxybenzene at 4 °C. \u003cb\u003e1\u003c/b\u003e shows a fascinating dielectric anomaly with a maximum at ca. 210 K, which is independent on ac frequency. However, the absence of thermal anomaly and structural phase transition is related to the dielectric anomaly. The co-crystal [4,4’-bipyridine]\u003csub\u003e2\u003c/sub\u003e[1,4-dihydroxybenzene-d\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e2\u003c/b\u003e) was further obtained via H\u003csup\u003e+\u003c/sup\u003e/D\u003csup\u003e+\u003c/sup\u003e exchange in \u003cb\u003e1\u003c/b\u003e and the deuteration gives rise to the maximum shifting to 254 K in the dielectric spectrum of \u003cb\u003e2\u003c/b\u003e. The dielectric anomaly corresponds to disorder-to-order transformation of H\u003csup\u003e+\u003c/sup\u003e/D\u003csup\u003e+\u003c/sup\u003e in the O-H/D…N H-bond in \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/articles/dataset/Dielectric_anomaly_and_giant_deuteration_effect_in_a_H_bond_trimeric_co_crystal_4_4_bipyridine_sub_2_sub_1_4_dihydroxybenzene_/3122941/1","contentUrl":null,"metadataVersion":5,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":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