{"data":{"id":"10.6084/m9.figshare.3122941","type":"dois","attributes":{"doi":"10.6084/m9.figshare.3122941","prefix":"10.6084","suffix":"m9.figshare.3122941","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Xiao-Zu Wang","affiliation":[],"nameIdentifiers":[]},{"name":"Xue, Qian","nameType":"Personal","givenName":"Qian","familyName":"Xue","affiliation":[],"nameIdentifiers":[]},{"name":"Liu, Shao-Xian","nameType":"Personal","givenName":"Shao-Xian","familyName":"Liu","affiliation":[],"nameIdentifiers":[]},{"name":"Luo, Hong-Bin","nameType":"Personal","givenName":"Hong-Bin","familyName":"Luo","affiliation":[],"nameIdentifiers":[]},{"name":"Ren, Xiao-Ming","nameType":"Personal","givenName":"Xiao-Ming","familyName":"Ren","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Dielectric anomaly and giant deuteration effect in a H-bond trimeric co-crystal [4, 4'-Bipyridine]\u003csub\u003e2\u003c/sub\u003e[1,4-dihydroxybenzene]"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Developmental Biology"},{"subject":"Inorganic Chemistry"},{"subject":"Computational Biology"}],"contributors":[],"dates":[{"date":"2016-03-23","dateType":"Created"},{"date":"2016-07-11","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/1539445x.2016.1159577","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["3739370 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Co-crystal [4,4\u003cb\u003eʹ\u003c/b\u003e-bipyridine]\u003csub\u003e2\u003c/sub\u003e[1,4-dihydroxybenzene] (\u003cb\u003e1\u003c/b\u003e) was prepared by evaporating methanol solution of 4,4\u003cb\u003eʹ\u003c/b\u003e-bipyridine with 1,4-dihydroxybenzene at 4°C. \u003cb\u003e1\u003c/b\u003e shows a fascinating dielectric anomaly with a maximum at ~210 K, which is independent on ac frequency. However, the absence of thermal anomaly and structural phase transition is related to the dielectric anomaly. The co-crystal [4,4\u003cb\u003eʹ\u003c/b\u003e-bipyridine]\u003csub\u003e2\u003c/sub\u003e[1,4-dihydroxybenzene-d\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e2\u003c/b\u003e) was further obtained via H\u003csup\u003e+\u003c/sup\u003e/D\u003csup\u003e+\u003c/sup\u003e exchange in \u003cb\u003e1\u003c/b\u003e and the deuteration gives rise to the maximum shifting to 254 K in the dielectric spectrum of \u003cb\u003e2\u003c/b\u003e. The dielectric anomaly corresponds to disorder-to-order transformation of H\u003csup\u003e+\u003c/sup\u003e/D\u003csup\u003e+\u003c/sup\u003e in the O–H/D···N H-bond in \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjEvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLjMxMjI5NDE8L2lkZW50aWZpZXI+CiAgPGNyZWF0b3JzPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5YaWFvLVp1IFdhbmc8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5RaWFuIFh1ZTwvY3JlYXRvck5hbWU+CiAgICA8L2NyZWF0b3I+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPlNoYW8tWGlhbiBMaXU8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5Ib25nLUJpbiBMdW88L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5YaWFvLU1pbmcgUmVuPC9jcmVhdG9yTmFtZT4KICAgIDwvY3JlYXRvcj4KICA8L2NyZWF0b3JzPgogIDx0aXRsZXM+CiAgICA8dGl0bGU+RGllbGVjdHJpYyBhbm9tYWx5IGFuZCBnaWFudCBkZXV0ZXJhdGlvbiBlZmZlY3QgaW4gYSBILWJvbmQgdHJpbWVyaWMgY28tY3J5c3RhbCBbNCwgNCctQmlweXJpZGluZV0mbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDtbMSw0LWRpaHlkcm94eWJlbnplbmVdPC90aXRsZT4KICA8L3RpdGxlcz4KICA8ZGVzY3JpcHRpb25zPgogICAgPGRlc2NyaXB0aW9uIGRlc2NyaXB0aW9uVHlwZT0iQWJzdHJhY3QiPiZsdDtwJmd0O0NvLWNyeXN0YWwgWzQsNCZsdDtiJmd0O8q5Jmx0Oy9iJmd0Oy1iaXB5cmlkaW5lXSZsdDtzdWImZ3Q7MiZsdDsvc3ViJmd0O1sxLDQtZGloeWRyb3h5YmVuemVuZV0gKCZsdDtiJmd0OzEmbHQ7L2ImZ3Q7KSB3YXMgcHJlcGFyZWQgYnkgZXZhcG9yYXRpbmcgbWV0aGFub2wgc29sdXRpb24gb2YgNCw0Jmx0O2ImZ3Q7yrkmbHQ7L2ImZ3Q7LWJpcHlyaWRpbmUgd2l0aCAxLDQtZGloeWRyb3h5YmVuemVuZSBhdCA0wrBDLiAmbHQ7YiZndDsxJmx0Oy9iJmd0OyBzaG93cyBhIGZhc2NpbmF0aW5nIGRpZWxlY3RyaWMgYW5vbWFseSB3aXRoIGEgbWF4aW11bSBhdCB+MjEwIEssIHdoaWNoIGlzIGluZGVwZW5kZW50IG9uIGFjIGZyZXF1ZW5jeS4gSG93ZXZlciwgdGhlIGFic2VuY2Ugb2YgdGhlcm1hbCBhbm9tYWx5IGFuZCBzdHJ1Y3R1cmFsIHBoYXNlIHRyYW5zaXRpb24gaXMgcmVsYXRlZCB0byB0aGUgZGllbGVjdHJpYyBhbm9tYWx5LiBUaGUgY28tY3J5c3RhbCBbNCw0Jmx0O2ImZ3Q7yrkmbHQ7L2ImZ3Q7LWJpcHlyaWRpbmVdJmx0O3N1YiZndDsyJmx0Oy9zdWImZ3Q7WzEsNC1kaWh5ZHJveHliZW56ZW5lLWQmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDtdICgmbHQ7YiZndDsyJmx0Oy9iJmd0Oykgd2FzIGZ1cnRoZXIgb2J0YWluZWQgdmlhIEgmbHQ7c3VwJmd0OysmbHQ7L3N1cCZndDsvRCZsdDtzdXAmZ3Q7KyZsdDsvc3VwJmd0OyBleGNoYW5nZSBpbiAmbHQ7YiZndDsxJmx0Oy9iJmd0OyBhbmQgdGhlIGRldXRlcmF0aW9uIGdpdmVzIHJpc2UgdG8gdGhlIG1heGltdW0gc2hpZnRpbmcgdG8gMjU0IEsgaW4gdGhlIGRpZWxlY3RyaWMgc3BlY3RydW0gb2YgJmx0O2ImZ3Q7MiZsdDsvYiZndDsuIFRoZSBkaWVsZWN0cmljIGFub21hbHkgY29ycmVzcG9uZHMgdG8gZGlzb3JkZXItdG8tb3JkZXIgdHJhbnNmb3JtYXRpb24gb2YgSCZsdDtzdXAmZ3Q7KyZsdDsvc3VwJmd0Oy9EJmx0O3N1cCZndDsrJmx0Oy9zdXAmZ3Q7IGluIHRoZSBP4oCTSC9EwrfCt8K3TiBILWJvbmQgaW4gJmx0O2ImZ3Q7MSZsdDsvYiZndDsgYW5kICZsdDtiJmd0OzImbHQ7L2ImZ3Q7LiZsdDsvcCZndDs8L2Rlc2NyaXB0aW9uPgogIDwvZGVzY3JpcHRpb25zPgogIDxzdWJqZWN0cz4KICAgIDxzdWJqZWN0PkJpb3BoeXNpY3M8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5CaW9jaGVtaXN0cnk8L3N1YmplY3Q+CiAgICA8c3ViamVjdCBzY2hlbWVVUkk9Imh0dHA6Ly93d3cuYWJzLmdvdi5hdS9hdXNzdGF0cy9hYnNALm5zZi8wLzZCQjQyN0FCOTY5NkMyMjVDQTI1NzQxODAwMDQ0NjNFIiBzdWJqZWN0U2NoZW1lPSJGT1IiPjI5OTk5IFBoeXNpY2FsIFNjaWVuY2VzIG5vdCBlbHNld2hlcmUgY2xhc3NpZmllZDwvc3ViamVjdD4KICAgIDxzdWJqZWN0IHNjaGVtZVVSST0iaHR0cDovL3d3dy5hYnMuZ292LmF1L2F1c3N0YXRzL2Fic0AubnNmLzAvNkJCNDI3QUI5Njk2QzIyNUNBMjU3NDE4MDAwNDQ2M0UiIHN1YmplY3RTY2hlbWU9IkZPUiI+Mzk5OTkgQ2hlbWljYWwgU2NpZW5jZXMgbm90IGVsc2V3aGVyZSBjbGFzc2lmaWVkPC9zdWJqZWN0PgogICAgPHN1YmplY3Q+RWNvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkRldmVsb3BtZW50YWwgQmlvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0Pklub3JnYW5pYyBDaGVtaXN0cnk8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Db21wdXRhdGlvbmFsICBCaW9sb2d5PC9zdWJqZWN0PgogIDwvc3ViamVjdHM+CiAgPHB1Ymxpc2hlcj5UYXlsb3IgJmFtcDsgRnJhbmNpczwvcHVibGlzaGVyPgogIDxwdWJsaWNhdGlvblllYXI+MjAxNjwvcHVibGljYXRpb25ZZWFyPgogIDxkYXRlcz4KICAgIDxkYXRlIGRhdGVUeXBlPSJDcmVhdGVkIj4yMDE2LTAzLTIzPC9kYXRlPgogICAgPGRhdGUgZGF0ZVR5cGU9IlVwZGF0ZWQiPjIwMTYtMDctMTE8L2RhdGU+CiAgPC9kYXRlcz4KICA8cmVzb3VyY2VUeXBlIHJlc291cmNlVHlwZUdlbmVyYWw9IkRhdGFzZXQiPkRhdGFzZXQ8L3Jlc291cmNlVHlwZT4KICA8c2l6ZXM+CiAgICA8c2l6ZT4zNzM5MzcwIEJ5dGVzPC9zaXplPgogIDwvc2l6ZXM+CiAgPHJlbGF0ZWRJZGVudGlmaWVycz4KICAgIDxyZWxhdGVkSWRlbnRpZmllciByZWxhdGVkSWRlbnRpZmllclR5cGU9IkRPSSIgcmVsYXRpb25UeXBlPSJJc1N1cHBsZW1lbnRUbyI+MTAuMTA4MC8xNTM5NDQ1WC4yMDE2LjExNTk1Nzc8L3JlbGF0ZWRJZGVudGlmaWVyPgogIDwvcmVsYXRlZElkZW50aWZpZXJzPgogIDxyaWdodHNMaXN0PgogICAgPHJpZ2h0cyByaWdodHNVUkk9Imh0dHBzOi8vY3JlYXRpdmVjb21tb25zLm9yZy9saWNlbnNlcy9ieS80LjAvIj5DQyBCWSA0LjA8L3JpZ2h0cz4KICA8L3JpZ2h0c0xpc3Q+CjwvcmVzb3VyY2U+","url":"https://tandf.figshare.com/articles/dataset/Dielectric_anomaly_and_giant_deuteration_effect_in_a_H_bond_trimeric_co_crystal_4_4_bipyridine_sub_2_sub_1_4_dihydroxybenzene_/3122941/2","contentUrl":null,"metadataVersion":6,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":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