{"data":{"id":"10.6084/m9.figshare.1394708","type":"dois","attributes":{"doi":"10.6084/m9.figshare.1394708","prefix":"10.6084","suffix":"m9.figshare.1394708","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Mughal, Maqsood Ali","nameType":"Personal","givenName":"Maqsood Ali","familyName":"Mughal","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Elemental sulfur-based electrodeposition of indium sulfide films"}],"publisher":"figshare","container":{},"publicationYear":2015,"subjects":[{"subject":"Solar System, Solar Physics, Planets and Exoplanets"},{"subject":"30604 Electrochemistry","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"30102 Electroanalytical Chemistry","subjectScheme":"FOR"},{"subject":"30303 Optical Properties of Materials","subjectScheme":"FOR"},{"subject":"30304 Physical Chemistry of Materials","subjectScheme":"FOR"},{"subject":"30306 Synthesis of Materials","subjectScheme":"FOR"},{"subject":"91305 Energy Generation, Conversion and Storage Engineering","subjectScheme":"FOR"},{"subject":"FOS: Mechanical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Mechanical engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"99902 Engineering Instrumentation","subjectScheme":"FOR"},{"subject":"FOS: Other engineering and technologies","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Other engineering and technologies","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91299 Materials Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91207 Metals and Alloy Materials","subjectScheme":"FOR"},{"subject":"90608 Renewable Power and Energy Systems Engineering (excl. Solar Cells)","subjectScheme":"FOR"},{"subject":"FOS: Electrical engineering, electronic engineering, information engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Electrical engineering, electronic engineering, information engineering","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2015-04-27","dateType":"Created"},{"date":"2016-06-15","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[],"relatedItems":[],"sizes":["272796 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"We report research on electrodeposition of indium sulfide films, with In2S3 a less hazardous alternative to CdS buffer layers in solar cells. Numerous organic and aqueous/organic electrolytes of InCl3, NaCl, and elemental sulfur were investigated, including several glycols and amides. Temperatures ranged from 80-170°C, and deposition voltages from -0.6 to -1.2 V (Ag/AgCl with organic filling solution). Substrates included indium tin oxide-on-glass, molybdenum, and titanium, with indium or graphite anodes. Rapid stirring was used. Deposition was sluggish in all baths. Uniformity and adherence were only moderate, with irregular coverage and cracking-and-flaking sometimes evident. The best baths were ethylene glycol or 1, 2-propanediol-based, with golden-yellow films, nominally In2S3-xOx, depositing typically heavier around the substrate edges. With low temperatures and/or large currents, brown films more rich in indium sometimes formed. Cyclic voltammetry elucidated onset potentials, secondary reactions, and photoactivity, with the greatest anodic photocurrents arising from In2S3's n-type conductivity occurring with mixed ethylene glycol/propionic acid/water baths. Scanning electron microscope photographs indicated a compact small grain microstructure for yellow films. Energy dispersive X-ray analysis and photoelectron spectroscopy data indicate up to 15% oxygen 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