{"data":{"id":"10.6084/m9.figshare.1183476.v3","type":"dois","attributes":{"doi":"10.6084/m9.figshare.1183476.v3","prefix":"10.6084","suffix":"m9.figshare.1183476.v3","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Tchatchouang, Marius","nameType":"Personal","givenName":"Marius","familyName":"Tchatchouang","affiliation":[],"nameIdentifiers":[]},{"name":"Mama Nsangou","affiliation":[],"nameIdentifiers":[]},{"name":"Ousmanou Motapon","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Stability, metastability and spectroscopic constants of electronic states of NH\u003csup\u003e−\u003c/sup\u003e and CH\u003csup\u003e−\u003c/sup\u003e"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Hematology"},{"subject":"Inorganic Chemistry"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Mathematics"},{"subject":"FOS: Mathematics","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Mathematics","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biological Sciences"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Physics"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-02-27","dateType":"Created"},{"date":"2016-01-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00268976.2014.963183","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.1183476","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["3014458 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Highly correlated \u003ci\u003eab initio\u003c/i\u003e methods were used in order to calculate potential energy curves (PECs) of the bound electronic states of CH\u003csup\u003e−\u003c/sup\u003e and NH\u003csup\u003e−\u003c/sup\u003e anions and the long-range parts of their excited states. The spin–orbit interaction between electronic states has been calculated for the cases in which the couplings were assumed to be responsible for perturbations. The spectroscopic constants of bound states were calculated from the PECs and compared with previous theoretical and/or available experimental values. Also, from the ground states of CH/CH\u003csup\u003e−\u003c/sup\u003e and NH/NH\u003csup\u003e−\u003c/sup\u003e, the adiabatic electron affinities were given and discussed.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/articles/dataset/Stability_metastability_and_spectroscopic_constants_of_electronic_states_of_NH_sup_8722_sup_and_CH_sup_8722_sup_/1183476/3","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":22,"viewsOverTime":[{"yearMonth":"2025-09","total":8},{"yearMonth":"2025-10","total":7},{"yearMonth":"2025-12","total":7}],"downloadCount":0,"downloadsOverTime":[{"yearMonth":"2025-09","total":0},{"yearMonth":"2025-10","total":0},{"yearMonth":"2025-12","total":0}],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2016-01-19T08:22:33.000Z","registered":"2016-01-19T08:22:34.000Z","published":"2015","updated":"2020-09-04T21:18:58.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.1183476.v3","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}