{"data":{"id":"10.6084/m9.figshare.1170131.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.1170131.v1","prefix":"10.6084","suffix":"m9.figshare.1170131.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Lukáš Jeremias","affiliation":[],"nameIdentifiers":[]},{"name":"Demo, Gabriel","nameType":"Personal","givenName":"Gabriel","familyName":"Demo","affiliation":[],"nameIdentifiers":[]},{"name":"Kubát, Václav","nameType":"Personal","givenName":"Václav","familyName":"Kubát","affiliation":[],"nameIdentifiers":[]},{"name":"Zdeněk Trávníček","affiliation":[],"nameIdentifiers":[]},{"name":"Novosad, Josef","nameType":"Personal","givenName":"Josef","familyName":"Novosad","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and \u003ci\u003eN\u003c/i\u003e-Donor Ligands"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2014,"subjects":[{"subject":"Mathematics"},{"subject":"FOS: Mathematics","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Mathematics","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biological Sciences"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Clinical medicine","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Molecular Biology"},{"subject":"Cell Biology"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2014-10-03","dateType":"Created"},{"date":"2016-01-19","dateType":"Updated"},{"date":"2014","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/10426507.2014.902825","relatedIdentifierType":"DOI"},{"relationType":"IsPreviousVersionOf","relatedIdentifier":"10.6084/m9.figshare.1170131","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["282693 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"A series of zinc(II) and cadmium(II) complexes, involving a combination of \u003ci\u003eS\u003c/i\u003e–donor (xanthates and dithiophosphates) and \u003ci\u003eN\u003c/i\u003e-donor (1,10-phen = 1,10-phenanthroline, 2,2′–bipy = 2,2′-bipyridine) ligands, of the composition [Cd(S\u003csub\u003e2\u003c/sub\u003eCO\u003ci\u003en\u003c/i\u003ePr)\u003csub\u003e2\u003c/sub\u003e(2,2′-bipy)] \u003cb\u003e(1)\u003c/b\u003e, [Cd(S\u003csub\u003e2\u003c/sub\u003eCO\u003ci\u003en\u003c/i\u003ePr)\u003csub\u003e2\u003c/sub\u003e(1,10-phen)] \u003cb\u003e(2)\u003c/b\u003e, [Cd(S\u003csub\u003e2\u003c/sub\u003eP(OEt)\u003csub\u003e2\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e(2,2′-bipy)] \u003cb\u003e(3)\u003c/b\u003e, [Cd(S\u003csub\u003e2\u003c/sub\u003eP(OEt)\u003csub\u003e2\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e(1,10-phen)] \u003cb\u003e(4)\u003c/b\u003e, [Zn(S\u003csub\u003e2\u003c/sub\u003eCO\u003ci\u003en\u003c/i\u003ePr)\u003csub\u003e2\u003c/sub\u003e(2,2′-bipy)] \u003cb\u003e(5)\u003c/b\u003e, [Zn(S\u003csub\u003e2\u003c/sub\u003eCO\u003ci\u003en\u003c/i\u003ePr)\u003csub\u003e2\u003c/sub\u003e(1,10-phen)] \u003cb\u003e(6)\u003c/b\u003e, [Zn(S\u003csub\u003e2\u003c/sub\u003eP(OEt)\u003csub\u003e2\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e(2,2′-bipy)] \u003cb\u003e(7)\u003c/b\u003e, and [Zn(S\u003csub\u003e2\u003c/sub\u003eP(OEt)\u003csub\u003e2\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e(1,10-phen)] \u003cb\u003e(8)\u003c/b\u003e was prepared. The complexes (\u003cb\u003e1\u003c/b\u003e–\u003cb\u003e8\u003c/b\u003e) were characterized by elemental analysis and single-crystal X-ray analysis. X-ray structures revealed that the coordination geometries vary from octahedral (complexes \u003cb\u003e1\u003c/b\u003e–\u003cb\u003e4\u003c/b\u003e), through square-pyramidal (complexes \u003cb\u003e5\u003c/b\u003e and \u003cb\u003e6\u003c/b\u003e) to tetrahedral (complexes \u003cb\u003e7\u003c/b\u003e and \u003cb\u003e8\u003c/b\u003e), depending on a combination of the central metal atoms and the corresponding \u003ci\u003eS\u003c/i\u003e-donor and \u003ci\u003eN\u003c/i\u003e-donor ligands. Similarities and discrepancies among the individual molecular structures as well as noncovalent contacts stabilizing crystal structures are discussed in more detail.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjEvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLjExNzAxMzEuVjE8L2lkZW50aWZpZXI+CiAgPGNyZWF0b3JzPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5MdWvDocWhIEplcmVtaWFzPC9jcmVhdG9yTmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+R2FicmllbCBEZW1vPC9jcmVhdG9yTmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+VsOhY2xhdiBLdWLDoXQ8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5aZGVuxJtrIFRyw6F2bsOtxI1lazwvY3JlYXRvck5hbWU+CiAgICA8L2NyZWF0b3I+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPkpvc2VmIE5vdm9zYWQ8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogIDwvY3JlYXRvcnM+CiAgPHRpdGxlcz4KICAgIDx0aXRsZT5TeW50aGVzaXMgYW5kIFgtUmF5IFN0cnVjdHVyZXMgb2YgWmluYyhJSSkgYW5kIENhZG1pdW0oSUkpIEhldGVyb2xlcHRpYyBDb21wbGV4ZXMgSW52b2x2aW5nIDEsMS1EaXRoaW9sYXRlIGFuZCAmbHQ7aSZndDtOJmx0Oy9pJmd0Oy1Eb25vciBMaWdhbmRzPC90aXRsZT4KICA8L3RpdGxlcz4KICA8ZGVzY3JpcHRpb25zPgogICAgPGRlc2NyaXB0aW9uIGRlc2NyaXB0aW9uVHlwZT0iQWJzdHJhY3QiPiZsdDtkaXYmZ3Q7Jmx0O3AmZ3Q7Jmx0Oy9wJmd0OyZsdDtwJmd0O0Egc2VyaWVzIG9mIHppbmMoSUkpIGFuZCBjYWRtaXVtKElJKSBjb21wbGV4ZXMsIGludm9sdmluZyBhIGNvbWJpbmF0aW9uIG9mICZsdDtpJmd0O1MmbHQ7L2kmZ3Q74oCTZG9ub3IgKHhhbnRoYXRlcyBhbmQgZGl0aGlvcGhvc3BoYXRlcykgYW5kICZsdDtpJmd0O04mbHQ7L2kmZ3Q7LWRvbm9yICgxLDEwLXBoZW4gPSAxLDEwLXBoZW5hbnRocm9saW5lLCAyLDLigLLigJNiaXB5ID0gMiwy4oCyLWJpcHlyaWRpbmUpIGxpZ2FuZHMsIG9mIHRoZSBjb21wb3NpdGlvbiBbQ2QoUyZsdDtzdWImZ3Q7MiZsdDsvc3ViJmd0O0NPJmx0O2kmZ3Q7biZsdDsvaSZndDtQcikmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDsoMiwy4oCyLWJpcHkpXSAmbHQ7YiZndDsoMSkmbHQ7L2ImZ3Q7LCBbQ2QoUyZsdDtzdWImZ3Q7MiZsdDsvc3ViJmd0O0NPJmx0O2kmZ3Q7biZsdDsvaSZndDtQcikmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDsoMSwxMC1waGVuKV0gJmx0O2ImZ3Q7KDIpJmx0Oy9iJmd0OywgW0NkKFMmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDtQKE9FdCkmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDspJmx0O3N1YiZndDsyJmx0Oy9zdWImZ3Q7KDIsMuKAsi1iaXB5KV0gJmx0O2ImZ3Q7KDMpJmx0Oy9iJmd0OywgW0NkKFMmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDtQKE9FdCkmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDspJmx0O3N1YiZndDsyJmx0Oy9zdWImZ3Q7KDEsMTAtcGhlbildICZsdDtiJmd0Oyg0KSZsdDsvYiZndDssIFtabihTJmx0O3N1YiZndDsyJmx0Oy9zdWImZ3Q7Q08mbHQ7aSZndDtuJmx0Oy9pJmd0O1ByKSZsdDtzdWImZ3Q7MiZsdDsvc3ViJmd0OygyLDLigLItYmlweSldICZsdDtiJmd0Oyg1KSZsdDsvYiZndDssIFtabihTJmx0O3N1YiZndDsyJmx0Oy9zdWImZ3Q7Q08mbHQ7aSZndDtuJmx0Oy9pJmd0O1ByKSZsdDtzdWImZ3Q7MiZsdDsvc3ViJmd0OygxLDEwLXBoZW4pXSAmbHQ7YiZndDsoNikmbHQ7L2ImZ3Q7LCBbWm4oUyZsdDtzdWImZ3Q7MiZsdDsvc3ViJmd0O1AoT0V0KSZsdDtzdWImZ3Q7MiZsdDsvc3ViJmd0OykmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDsoMiwy4oCyLWJpcHkpXSAmbHQ7YiZndDsoNykmbHQ7L2ImZ3Q7LCBhbmQgW1puKFMmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDtQKE9FdCkmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDspJmx0O3N1YiZndDsyJmx0Oy9zdWImZ3Q7KDEsMTAtcGhlbildICZsdDtiJmd0Oyg4KSZsdDsvYiZndDsgd2FzIHByZXBhcmVkLiBUaGUgY29tcGxleGVzICgmbHQ7YiZndDsxJmx0Oy9iJmd0O+KAkyZsdDtiJmd0OzgmbHQ7L2ImZ3Q7KSB3ZXJlIGNoYXJhY3Rlcml6ZWQgYnkgZWxlbWVudGFsIGFuYWx5c2lzIGFuZCBzaW5nbGUtY3J5c3RhbCBYLXJheSBhbmFseXNpcy4gWC1yYXkgc3RydWN0dXJlcyByZXZlYWxlZCB0aGF0IHRoZSBjb29yZGluYXRpb24gZ2VvbWV0cmllcyB2YXJ5IGZyb20gb2N0YWhlZHJhbCAoY29tcGxleGVzICZsdDtiJmd0OzEmbHQ7L2ImZ3Q74oCTJmx0O2ImZ3Q7NCZsdDsvYiZndDspLCB0aHJvdWdoIHNxdWFyZS1weXJhbWlkYWwgKGNvbXBsZXhlcyAmbHQ7YiZndDs1Jmx0Oy9iJmd0OyBhbmQgJmx0O2ImZ3Q7NiZsdDsvYiZndDspIHRvIHRldHJhaGVkcmFsIChjb21wbGV4ZXMgJmx0O2ImZ3Q7NyZsdDsvYiZndDsgYW5kICZsdDtiJmd0OzgmbHQ7L2ImZ3Q7KSwgZGVwZW5kaW5nIG9uIGEgY29tYmluYXRpb24gb2YgdGhlIGNlbnRyYWwgbWV0YWwgYXRvbXMgYW5kIHRoZSBjb3JyZXNwb25kaW5nICZsdDtpJmd0O1MmbHQ7L2kmZ3Q7LWRvbm9yIGFuZCAmbHQ7aSZndDtOJmx0Oy9pJmd0Oy1kb25vciBsaWdhbmRzLiBTaW1pbGFyaXRpZXMgYW5kIGRpc2NyZXBhbmNpZXMgYW1vbmcgdGhlIGluZGl2aWR1YWwgbW9sZWN1bGFyIHN0cnVjdHVyZXMgYXMgd2VsbCBhcyBub25jb3ZhbGVudCBjb250YWN0cyBzdGFiaWxpemluZyBjcnlzdGFsIHN0cnVjdHVyZXMgYXJlIGRpc2N1c3NlZCBpbiBtb3JlIGRldGFpbC4mbHQ7L3AmZ3Q7Jmx0Oy9kaXYmZ3Q7PC9kZXNjcmlwdGlvbj4KICA8L2Rlc2NyaXB0aW9ucz4KICA8c3ViamVjdHM+CiAgICA8c3ViamVjdD5NYXRoZW1hdGljczwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkJpb2xvZ2ljYWwgU2NpZW5jZXM8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5JbW11bm9sb2d5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+Q2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+RWFydGggYW5kIEVudmlyb25tZW50YWwgU2NpZW5jZXM8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Nb2xlY3VsYXIgQmlvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkNlbGwgQmlvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkJpb2NoZW1pc3RyeTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkJpb3BoeXNpY3M8L3N1YmplY3Q+CiAgPC9zdWJqZWN0cz4KICA8cHVibGlzaGVyPlRheWxvciAmYW1wOyBGcmFuY2lzPC9wdWJsaXNoZXI+CiAgPHB1YmxpY2F0aW9uWWVhcj4yMDE0PC9wdWJsaWNhdGlvblllYXI+CiAgPGRhdGVzPgogICAgPGRhdGUgZGF0ZVR5cGU9IkNyZWF0ZWQiPjIwMTQtMTAtMDM8L2RhdGU+CiAgICA8ZGF0ZSBkYXRlVHlwZT0iVXBkYXRlZCI+MjAxNi0wMS0xOTwvZGF0ZT4KICA8L2RhdGVzPgogIDxyZXNvdXJjZVR5cGUgcmVzb3VyY2VUeXBlR2VuZXJh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