{"data":{"id":"10.6084/m9.figshare.1121497.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.1121497.v1","prefix":"10.6084","suffix":"m9.figshare.1121497.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Seyyed Javad Sabounchei","affiliation":[],"nameIdentifiers":[]},{"name":"Mozafari, Zeinab","nameType":"Personal","givenName":"Zeinab","familyName":"Mozafari","affiliation":[],"nameIdentifiers":[]},{"name":"Fateme Akhlaghi Bagherjeri","affiliation":[],"nameIdentifiers":[]},{"name":"Khavasi, Hamid Reza","nameType":"Personal","givenName":"Hamid Reza","familyName":"Khavasi","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Transition Metal Complexes of α-keto Stabilized Sulfonium Ylides: Linear in Contrast to Bridging Structure in Silver(I) Complexes"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Mathematics"},{"subject":"FOS: Mathematics","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Mathematics","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biological Sciences"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Cell Biology"},{"subject":"Biochemistry"}],"contributors":[],"dates":[{"date":"2015-02-25","dateType":"Created"},{"date":"2016-01-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/10426507.2014.947404","relatedIdentifierType":"DOI"},{"relationType":"IsPreviousVersionOf","relatedIdentifier":"10.6084/m9.figshare.1121497","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["2708948 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"The reactions of α-keto stabilized sulfonium ylide (Me)\u003csub\u003e2\u003c/sub\u003eSCHC(O)C\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003e-m-NO\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003eY\u003csub\u003e1\u003c/sub\u003e\u003c/b\u003e) with HgX\u003csub\u003e2\u003c/sub\u003e (X = Cl (\u003cb\u003e1\u003c/b\u003e), Br (\u003cb\u003e2\u003c/b\u003e) and I (\u003cb\u003e3\u003c/b\u003e)) in equimolar ratios and CdCl\u003csub\u003e2\u003c/sub\u003e.H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e4\u003c/b\u003e) in 1:2 molar ratio using methanol as a solvent lead to binuclear Hg(II) complexes and a polymeric Cd(II) organic-inorganic hybrid. Furthermore, from the reaction of sulfonium ylides (\u003cb\u003eY\u003csub\u003e1\u003c/sub\u003e\u003c/b\u003e), (Me)\u003csub\u003e2\u003c/sub\u003eSCHC(O)C\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003e-p-NO\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003eY\u003csub\u003e2\u003c/sub\u003e\u003c/b\u003e) and (Me)\u003csub\u003e2\u003c/sub\u003eSCHC(O)C\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003e-p-OMe (\u003cb\u003eY\u003csub\u003e3\u003c/sub\u003e\u003c/b\u003e) with AgTfO in 2: 1 molar ratio using dichloromethane as a solvent, [Ag(Y\u003csub\u003en\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e]TfO (n = 1 (\u003cb\u003e5\u003c/b\u003e), n = 2 (\u003cb\u003e6\u003c/b\u003e), n = 3 (\u003cb\u003e7\u003c/b\u003e)) complexes were obtained. Single crystal X-ray diffraction analysis reveals the presence of linear structure for \u003cb\u003e5\u003c/b\u003e. Characterization of the obtained compounds was also performed by elemental analysis, IR, \u003csup\u003e1\u003c/sup\u003eH- and \u003csup\u003e13\u003c/sup\u003eC- NMR.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/articles/dataset/Transition_Metal_Complexes_of_945_keto_Stabilized_Sulfonium_Ylides_Linear_in_Contrast_to_Bridging_Structure_in_Silver_I_Complexes/1121497/1","contentUrl":null,"metadataVersion":3,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2016-01-19T05:44:48.000Z","registered":"2016-01-19T05:44:49.000Z","published":"2015","updated":"2020-09-04T22:05:58.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.1121497.v1","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}