{"data":{"id":"10.6084/m9.figshare.1086293.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.1086293.v1","prefix":"10.6084","suffix":"m9.figshare.1086293.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Alireza Dadrass","affiliation":[],"nameIdentifiers":[]},{"name":"Hojjatollah Rahchamani","affiliation":[],"nameIdentifiers":[]},{"name":"Khalafy, Jabbar","nameType":"Personal","givenName":"Jabbar","familyName":"Khalafy","affiliation":[],"nameIdentifiers":[]},{"name":"Ramazani, Ali","nameType":"Personal","givenName":"Ali","familyName":"Ramazani","affiliation":[],"nameIdentifiers":[]},{"name":"Habashi, Bayram Parsa","nameType":"Personal","givenName":"Bayram Parsa","familyName":"Habashi","affiliation":[],"nameIdentifiers":[]},{"name":"Marjani, Ahmad Poursattar","nameType":"Personal","givenName":"Ahmad Poursattar","familyName":"Marjani","affiliation":[],"nameIdentifiers":[]},{"name":"Souldozi, Ali","nameType":"Personal","givenName":"Ali","familyName":"Souldozi","affiliation":[],"nameIdentifiers":[]},{"name":"Ślepokura, Katarzyna","nameType":"Personal","givenName":"Katarzyna","familyName":"Ślepokura","affiliation":[],"nameIdentifiers":[]},{"name":"Lis, Tadeusz","nameType":"Personal","givenName":"Tadeusz","familyName":"Lis","affiliation":[],"nameIdentifiers":[]},{"name":"Rouhani, Morteza","nameType":"Personal","givenName":"Morteza","familyName":"Rouhani","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Study of Conversion of Polymeric Organophosphorus Ylide Complexes of Mercury(ii) Halides to Phenazine Complexes: X-RAY Crystal Structures and Spectral Characterizations"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Mathematics"},{"subject":"FOS: Mathematics","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Mathematics","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biological Sciences"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Cell Biology"},{"subject":"Engineering"}],"contributors":[],"dates":[{"date":"2015-02-25","dateType":"Created"},{"date":"2016-01-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/10426507.2014.919291","relatedIdentifierType":"DOI"},{"relationType":"IsPreviousVersionOf","relatedIdentifier":"10.6084/m9.figshare.1086293","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["1192650 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"The reaction of PPh\u003csub\u003e3\u003c/sub\u003e with BrCH\u003csub\u003e2\u003c/sub\u003eC(O)PhNO\u003csub\u003e2\u003c/sub\u003e leads to a new phosphonium salt [Ph\u003csub\u003e3\u003c/sub\u003eP-CH\u003csub\u003e2\u003c/sub\u003eC(O)PhNO\u003csub\u003e2\u003c/sub\u003e]Br (\u003cb\u003e1\u003c/b\u003e). Reaction of the salt \u003cb\u003e1\u003c/b\u003e with an appropriate base gave the free ligand, Ph\u003csub\u003e3\u003c/sub\u003eP = C(H)C(O)PhNO\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003e2\u003c/b\u003e). The reactions of ligand \u003cb\u003e2\u003c/b\u003e with mercury(II) halides form the C-coordinated polymeric complexes [(\u003cb\u003e2\u003c/b\u003e)HgX\u003csub\u003e2\u003c/sub\u003e]\u003csub\u003en\u003c/sub\u003e {X = Cl (\u003cb\u003e3\u003c/b\u003e), Br (\u003cb\u003e4\u003c/b\u003e), I (\u003cb\u003e5\u003c/b\u003e)}. Reactions of benzo[\u003ci\u003ea\u003c/i\u003e]quinoxalino[2,3-\u003ci\u003ec\u003c/i\u003e]phenazine ligand (L) with complexes \u003cb\u003e3\u003c/b\u003e, \u003cb\u003e4\u003c/b\u003e and \u003cb\u003e5\u003c/b\u003e cause the removal of ylidic ligand and lead to the formation of a new set of mononuclear mercury halides complexes {[(L)HgCl\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e6\u003c/b\u003e), [(L)HgBr\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e7\u003c/b\u003e) and [(L)HgI\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e8\u003c/b\u003e)} containing (L\u003cb\u003e)\u003c/b\u003e as a bidentate ligand. The structures of \u003cb\u003e4\u003c/b\u003e and \u003cb\u003e6\u003c/b\u003e were confirmed by single-crystal X-ray analysis. The structure of the products were identified by IR, \u003csup\u003e1\u003c/sup\u003eH and \u003csup\u003e31\u003c/sup\u003eP NMR spectral data and elemental analysis.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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