{"data":{"id":"10.6084/m9.figshare.1061425","type":"dois","attributes":{"doi":"10.6084/m9.figshare.1061425","prefix":"10.6084","suffix":"m9.figshare.1061425","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Xiulin An","affiliation":[],"nameIdentifiers":[]},{"name":"Hongying Zhuo","affiliation":[],"nameIdentifiers":[]},{"name":"Wenkai Tian","affiliation":[],"nameIdentifiers":[]},{"name":"Qingzhong Li","affiliation":[],"nameIdentifiers":[]},{"name":"Wenzuo Li","affiliation":[],"nameIdentifiers":[]},{"name":"Jianbo Cheng","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Novel non-covalent interactions involved with the Al\u003csub\u003e13\u003c/sub\u003eM cluster (M = Li, Na, K, Cu, Ag, Au)"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2014,"subjects":[{"subject":"60506 Virology","subjectScheme":"FOR"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Hematology"},{"subject":"Cancer"},{"subject":"Biological Sciences"},{"subject":"Ecology"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Evolutionary Biology"},{"subject":"Medicine"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2014-06-19","dateType":"Created"},{"date":"2015-12-02","dateType":"Updated"},{"date":"2014","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00268976.2014.920114","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["20386432 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"The complexes of Al\u003csub\u003e13\u003c/sub\u003eM cluster (M = Li, Na, K, Cu, Ag, Au) and Lewis bases NH\u003csub\u003e3\u003c/sub\u003e, H\u003csub\u003e2\u003c/sub\u003eO, C\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e6\u003c/sub\u003e, and HLi have been predicted and characterised. The results showed that the cluster Al\u003csub\u003e13\u003c/sub\u003eM forms the alkali-bonding or coinage metal-bonding interaction through M with these Lewis bases. These complexes exhibit some similarities and differences in the structures, properties, and nature with conventional molecules. The formation of these interactions has a negligible or small effect on the structures of Al\u003csub\u003e13\u003c/sub\u003eM. This study combines the cluster Al\u003csub\u003e13\u003c/sub\u003eM with non-covalent interactions, which is of great importance in supramolecular chemistry.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/articles/dataset/Novel_non_covalent_interactions_involved_with_the_Al_sub_13_sub_M_cluster_M_Li_Na_K_Cu_Ag_Au_/1061425","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2014-06-19T08:03:20.000Z","registered":"2014-06-19T08:03:21.000Z","published":"2014","updated":"2020-09-04T22:42:52.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"da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